You left out the best one where [EDIT] Old-Guy-Who-Dresses-Like-A-British-Soldier completely obliterated her. It was one of the DLs from late last year or early this year. [EDIT: 12-21-14, see pic.]
Also, why do you lower the quality of your edits to 480p when the originals are 1080p?
See my edited post... I confused the two "cartoon character" guys they always trot onto this program. The pieing is from 12-21-14, and as per the pic it's the best she ever took on this show.
The clip you're talking about is from the early days of the show, when they wouldn't upload in HD, so 480p is as good as it gets. This one is from the 1080p days.
So THAT's the girl who pied herself after getting pied (first clip). I love that clip. Like I said in another post, the majority of the women on these shows act like there's battery acid in the pies or something so it's fun to see a woman having some fun with it.
Too bad Captain OId Man wasn't smart enough to get another question right that day. He definitely pied the hell out of her, and based on the way she got him the rest of the time, the second pieing (if he hadn't been so dumb) would've been even better.
She's from one of those comedy shows on SBT (Ratinho?) along with Milene, Captain Old Man, Fake Nose Guy, and possibly Tall Young Balding Idiot Guy. Also the dark-skinned woman from The Noite with the insane hair is on SBT too, so she shows up a lot. All of these women are allowed to enjoy it and (more importantly) get pied WELL by the men, because they are not beautiful supermodels or celebrities, but simply SBT comic relief. Fortunately Valentina is pretty attractive. (Milene is "eh," and Crazy Afro Woman is consistently a waste of time.)