I've seen some adverts recently for a music duo called Mona Lisa. Specifically, they did a photo shoot for their "Orange" album including paint. (I don't think there's any corresponding video for it.)
I suspect that there's some degree of Photoshop involved here, particularly for the photos where their mouths are open. However, I think they probably did get some paint poured over them (e.g. for the final photo), even if it wasn't as dynamic as it looks.