From a show called mi corazon es tuyo. As I have gathered from my 10 seconds of investigation, the gal in question is a gold digger who tries to steal the hero character ( a stripper/nanny with a heart of gold)s billionaire boyfriend. Then apparently she talks some trash to the camera, gets some balls thrown at her, which really pisses her off. She gets up in the cameras grill, and bam! Pied!!!
Not the best pie, but I love love love this set up. She's hot and clearly a being a massive bitch. Scene starts at 25:20
YouTube has a few shitty cuts of this episode. I don't have capture ability but hulu has a much better HD streaming episode. Episode 176 and at 26:00 if you have hulu. (Go get hulu. It's awesome)
No kids in the scene, but literal babies in the episode. Like I said, no capture stuff, so I can't cut it up for you all.
Cause of the kids, I'm not gonna link it. But feel free to look it up, it's an easy search
MI corazon es tuyo El bautizo MI corazon es tuyo 176 parte 1
Thanks, Meathook! The YouTube search on your phrases turns up another couple of nice scenes, but they too unfortunately have kids in the clips. There is a nice green slime scene under "Mi Corazon Es Tuyo - La mejor travesura". There is a blue paint scene in that clip as well but a higher quality version of it can be found under "Mi Corazon Es Tuyo (2014) Los gemelos le arruinaron el cabello de Isabela".